Product ID:1,7,7-TRIMETHYLBICYCLO (2,2,1)-HEPTAN-2-ONE, O-799
MSDS Date:09/01/1988
FSC:6810
NIIN:00N067880
MSDS Number: CBGRH

Emergency Phone: 215-692-3026

Info Phone: 215-692-3026

Cage: 84898

Telephone: 610-692-3026

Cage: 8Y898

CAMPHOR, (1R,4R)-(+)-; (1,7,7-TRIMETHYLBICYCLO

CAS: 464-49-3

RTECS: EX1260000

OSHA PEL 2 PPM (MFR)

ACGIH TLV: 2 PPM (MFR)

LD50 LC50 Mixture:LD50:(ORAL,RAT) 1310 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ALL CHEMS SHOULD BE CONSIDERED HAZ -
AVOID DIRECT PHYSICAL CONT! CAN CAUSE EYE IRRIT. CAN CAUSE SKIN
IRRIT. CAN BE FATAL IF ABSORBED THRU SKIN! CAN BE FATAL IF INHALED!
MAY BE FATAL IF SWALLOWED! CAN BE HARMFUL IF ABSORBED THRU SKIN.
CAN BE HARMFUL IF INHALED. CAN BE HARMFUL IF SWALLOWED. PRLNG EXPOS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EXPOS MAY CAUSE NAUS/HDCH/DIZZ &/OR
EYE DMG. CAN BE IRRIT TO MUC MEMBS. CAN CAUSE ALLERGIC RESP RXN.
DUST &/OR VAPS CAN CAUSE IRRIT TO RESP TRACT. POSS CHOLINESTERASE
INHIBITOR-MAY CAUSE SEIZ URES; NAUS; VOMIT; AIRWAY OBSTRUCTION &/OR
INCR MUC SECRETIONS IN LUNGS. THIS CMPD IS CONSIDERED TO BE
SLIGHTLY TOXIC.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:CALL MD IMMED . EYES:FLUSH CONTINUOUSLY W/WATER FOR AT
LST 15-20 MINS. SKIN:FLUSH W/WATER FOR 15-20 MINS. IF NO BURNS HAVE
OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL:REMOVE PATIENT TO
FRESH AIR. ADMIN OXYG IF PATIENT IS HAVING DFCLTY BRTHG. IF PATIENT
HAS STOPPED BRTHG ADMIN ARTF RESP. IF PATIENT IS IN CARDIAC ARREST
ADMIN CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL MED(SUPDAT)

Flash Point:147F,64C
Lower Limits:0.6%
Upper Limits:3.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THIS IS A COMBUSTIBLE COMPOUND.

Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED
EQUIPMENT. VENTILATE AREA. SWEEP UP & PLACE IN AN APPROPRIATE
CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE
ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING.
KEEP TIGHTLY CLOSED & STORE IN A COOL, DRY PLACE. STORE ONLY
W/COMPATIBLE CHEMICALS.
Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD
NOT HANDLE THIS CHEM/ITS CNTNR. THIS PROD IS FURNISHED FOR LAB USE
ONLY! PRODS MAY NOT BE USED AS DRUGS, COSMETICS,
AGRICULTURAL/PESTICIDAL PRODS, FO OD ADDITIVES/AS HOUSEHOLD
CHEMICALS.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . USE APPROP NIOSH/MSHA APPROVED SAFETY EQUIP.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN IN THE
LABORATORY.
Supplemental Safety and Health
FIRST AID PROC:ASSISTANCE HAS ARRIVED. NOTE:AN ANTIDOTE IS A SUBSTANCE
INTENDED TO COUNTERACT EFT OF A POIS. IT SHOULD BE ADMINISTERED
ONLY BY MD/TRAINED EMER PERS. MED ADVICE CAN BE OBTAINED FROM A P
OIS CTL CTR.

Boiling Pt:B.P. Text:399F,204C
Melt/Freeze Pt:M.P/F.P Text:352F,178C
Vapor Pres:0.18 @ 20C
Spec Gravity:0.992
Solubility in Water:SLIGHTLY SOLUBLE
Appearance and Odor:WHITE CRYSTALLINE SOLID; CAMPHOR LIKE ODOR.

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/STRONG OXIDIZING AGENTS & STRONG REDUCING AGENTS.
Stability Condition to Avoid:COMBUSTIBLE. SENSITIVE TO LIGHT - DARK
COLOR DOES NOT AFFECT PURITY. SENSITIVE TO HEAT. DECOMP PRODUCTS
ARE CORROSIVE.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER
& SCRUBBER.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.